Composition of Murchison meteorite

Composition of Murchison meteorite

Introduction:

During the early days of the formation of the Earth, carbon-rich meteorites played a significant role in delivering organic molecules. Apart from enriching the crust of Earth with organic molecules, these meteorites also played a critical role in developing and evolving our home planet's atmosphere. Of the uncountable meteorites that fell on Earth, here we will discuss a particular one, the Murchison meteorite, in-depth.

Overview of Murchison:

In 1969, a meteorite with more than 100 kg of mass fell on the Australian village of Murchison. It was named Murchison (derived from its impact site). The meteorite was full of organic molecules and today it is one of the most studied meteorites of all the meteorites. The Murchison meteorite is older than the Earth and even the Solar System. More than 15 amino acids have been discovered from the Murchison till today. Silicon Carbide, the oldest material found on Earth was also detected in the Murchison meteorite. Advance studies proposed that the Murchison is full of carboxylic acids, hydrocarboxylic acids and fullerenes.

Chemistry of Murchison:

The diversity of organic compounds discovered on the Murchison helped researchers to understand the chemistry of early interstellar objects that existed before or at the time of the birth of the Solar System. More than 70% of the carbon content of the Murchison has been classified as (macromolecular) insoluble organic matter (IOM) of high aromaticity. This IOM is actually a major component of almost all interstellar objects. The high aromaticity can be directly linked to the high stability of these molecules.  

 
Composition of Murchison meteorite
Example of IOM found from Murchison

The samples of IOM from Murchison were studied by both, destructive and non-destructive methods. The destructive method includes chemical and thermal degradations followed by the GC/MS (gas chromatography/ mass spectrometry). Non- destructive methods mainly include various spectroscopic techniques like Fourier Transform Infrared Spectroscopy [FTIS], X- Ray Absorption Near Edge Spectroscopy [XANES] and Nuclear Magnetic Resonance [NMR].

Now let's understand this in easy language. Thermal degradation means the breaking of a molecule (or molecular chains) using heat. Similarly, chemical degradation uses chemical reactions to degrade or break the molecule. Gas chromatography is a technique used to separate and analyze the compounds that can be vaporized. Mass spectrometry is another analytical technique used to measure the mass to charge ratio of ions. In GC/MS, the applications of both techniques are combined for a more detailed analysis of the compound. 

FTIR as the name suggest is used to obtain the infrared spectrum of compounds. The implementation of this technique is a bit similar to the GC/MS. However, FTIR is now widely used due to its less sensitivity than the GC/MS. NMR is used to measure the magnetic field of the atomic nuclei of various compounds. The aromatic nature of the IOM compounds found from the Murchison was detected by the FTIR technique. 

Another technique that helped researchers to study the chemistry of Murchison was High-Resolution Transmission Electron Microscopy (HRTEM). HRTEM is a very efficient technique for the direct imaging of the atomic structure of any compound. Carbon-carbon bonding (especially sp² bonding). 

Further analysis of the meteorite samples using GC/MS resulted in the detection of xanthine, adenine, hypoxanthine, uracil and guanine. Xanthine is mainly found in human tissues and many plant cells. Guanine and Adenine are the building blocks of DNA. Uracil is a building block of RNA. The detection of these compounds revealed that the origin of life on Earth is highly impacted by the influence of extraterrestrial objects that fell on Earth. We can say that it is due to these meteorites that today we advanced and complex chemistry on Earth. The synthesis of protein on Earth is also believed to start after the impact of such meteorites. 

Composition of Murchison meteorite
Murchison meteorite at the The National Museum of Natural History (Washington)
Source : Wikimedia 

One can say that the meteorites like Murchison are the reason for the origin of organic compounds (and eventually life) on Earth. Apart from these compounds, various amino acids, nucleobases and different forms of sugar are also identified as major components of Murchison. It is important to note that xanthine and uracil are capable of self-association in monolayer structure. Continuous addition of meteoritic uracil and xanthine and some other nucleobases on land might have influenced prebiotic organic reactions necessary for the origin of life on Earth. One can say that the meteorites like Murchison are the reason for the origin of organic compounds (and eventually life) on Earth. Apart from these compounds, various amino acids, nucleobases and different forms of sugar are also identified as major components of Murchison.   

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